Nexus Series

● Simultaneously collects XRD and gas/vapor sorption data.
● High-power X-ray source (600–1600 W) with ±0.01° angular accuracy.
● Fully automated intelligent workflow.
● Four model configurations (Nexus G Core, Nexus G Cryo, Nexus GV Core, Nexus GV Cryo).

Introduction

What occurs when a material’s crystal structure interacts with its pore adsorption characteristics? How can researchers eliminate data barriers between different characterization methods, and advance from single-parameter testing to comprehensive, multi-parameter analysis?

The Nexus Series Integrated XRD–Sorption Analysis Platform delivers the answer. It synchronously collects X-ray diffraction data during gas and vapor physisorption experiments, creating direct, meaningful correlations between structural changes and adsorption behavior. The system simultaneously records crystallographic data — including crystal structure, lattice parameters, and phase composition — alongside key adsorption metrics such as adsorption isotherms, adsorption capacity, pore size distribution, and average pore diameter.

This enables end-to-end characterization across crystal structure, microscopic pore architecture, and macroscopic material performance. It reveals the causal links that govern material performance, improves the credibility of research results, and speeds up innovative development for catalysts, energy storage materials, and porous adsorbents.

 

Main Functions

  • Phase Search & Identification
  • Quantitative Phase Analysis
  • Crystallinity Analysis
  • Rietveld Refinement
  • Gas Adsorption-Desorption Isotherms
  • Full-Range Pore Size Distribution Analysis
  • Adsorption Kinetics
  • Isosteric Heat of Adsorption
  • In Situ Structural Refinement During Adsorption

KEY DIFFERENTIATORS

The Nexus Series is uniquely engineered to bridge crystallographic and sorption characterization in a single, fully integrated platform — eliminating the experimental gaps, sample transfer errors, and data inconsistencies that arise when XRD and adsorption analysis are performed as separate experiments on separate instruments.

 

Fully Automated Intelligent Workflow

XRD data acquisition is fully integrated into the adsorption measurement workflow. One-click operation enables completely automated experiments with unattended execution from start to finish, eliminating manual intervention between sorption and diffraction data collection steps.

 

High-Power X-ray Source

Features continuously adjustable X-ray tube power from 600 W to 1600 W for high-quality diffraction data acquisition across a wide range of sample types. Higher tube power improves the peak-to-background ratio and lowers detection limits for quantitative phase analysis — critical when characterizing materials undergoing structural evolution at low concentrations of a transforming phase.

 

Ultra-High Angular Accuracy

Achieves a 2θ angular accuracy of ±0.01°, verified against NIST-1976a corundum standard reference material, ensuring precise peak positioning and excellent agreement with standard reference materials. Peak position repeatability on the quartz SiO₂ (101) reflection demonstrates sub-millidegree reproducibility.

 

Direct Photon-Counting 2D Array Detector

Features a 256 × 256 pixel array with 55 × 55 μm pixel pitch for simultaneous signal acquisition across the full detector area. Provides high-resolution diffraction data with excellent signal-to-noise ratio (SNR). Selectable 0D, 1D, and 2D operating modes support a wide range of application requirements from routine powder diffraction through texture analysis and pair distribution function (PDF) measurements.

 

Minimized Dead-Volume In Situ Sample Stage

The in situ sample stage is engineered to minimize dead volume — the gas-phase volume not occupied by the sample. Minimizing dead volume is essential for accurate sorption measurements, particularly at low pressures in micropore characterization, where dead volume corrections can otherwise become a dominant source of error. The minimized dead volume design ensures that measured adsorption accurately reflects sample behavior rather than instrument geometry artifacts.

 

Multi-Range High-Precision Pressure Measurement

Features high-precision pressure transducers with ranges of 1000 Torr, 10 Torr, and 1 Torr (or 0.1 Torr), providing accurate pressure measurement from high vacuum through atmospheric pressure. This multi-range configuration supports both micropore analysis (requiring precise low-pressure measurement) and mesopore/macropore characterization (requiring accurate high-pressure measurement) in a single instrument without transducer switching.

 

Turbomolecular Pump High-Vacuum System

Features a turbomolecular pump backed by a mechanical pump, achieving the clean high vacuum required for reliable micropore characterization. An optimized, user-serviceable cold-trap manifold maintains an ultra-clean measurement environment, protecting the turbomolecular pump from condensable vapors and ensuring long-term system reliability in demanding research applications.

 

Temperature-Controlled In Situ Transfer System

The transfer line connecting the sorption system to the XRD stage features an independent temperature-control system that maintains a constant free volume throughout the experiment. This ensures accurate and reproducible measurements under in situ conditions, preventing condensation or adsorption of gas-phase species in the transfer line that would compromise the accuracy of the correlated XRD-sorption dataset.

 

Expandable Vapor Adsorption Capability (GV models)

The vapor generation module is housed within a temperature-controlled enclosure with a cold-spot-free design. This prevents vapor condensation at any point in the delivery pathway and ensures a stable, controlled vapor pressure for accurate and reliable vapor adsorption measurements — enabling characterization of water vapor, organic solvent vapors, and other adsorbates beyond the range of standard gas adsorption instruments.

 

Expandable BET Surface Area and Full-Range Pore Size Distribution

The Nexus Series supports full BET surface area measurement and complete pore size distribution analysis across the micro-, meso-, and macropore regimes in a single integrated experiment — simultaneously correlated with the evolving XRD structural data.

MODEL COMPARISON

The Nexus Series is available in four configurations defined by two independent axes: adsorbate type (gas only, or gas and vapor) and temperature operating range (ambient/elevated, or cryogenic/temperature-controlled):

Model Adsorbates Adsorption Temperature Range Best Suited For
Nexus G Core Non-corrosive gases only RT to 623 K (ambient and elevated temperature) Gas adsorption studies at ambient and high temperature — catalysts, MOFs, zeolites under thermal activation conditions
Nexus G Cryo Non-corrosive gases only 85 K to 473 K (cryogenic and temperature-controlled) Gas adsorption at cryogenic temperatures — N₂ adsorption at 77 K, Ar adsorption at 87 K, CO₂ adsorption at 195 K for micropore characterization
Nexus GV Core Non-corrosive gases and vapors RT to 623 K (ambient and elevated temperature) Combined gas and vapor adsorption at ambient/elevated temperatures — water vapor, organic solvent vapors, mixed gas-vapor systems
Nexus GV Cryo Non-corrosive gases and vapors 85 K to 473 K (cryogenic and temperature-controlled) Most complete configuration — gas and vapor adsorption across cryogenic through elevated temperature range

APPLICATIONS

The Nexus Series delivers unique scientific value whenever the correlation between crystal structure and adsorption behavior is the central research question. Standard separate-instrument workflows cannot answer this question with confidence because sample transfer, different experimental conditions, and batch-to-batch variation all introduce uncertainty into the XRD-sorption correlation. The Nexus Series eliminates these variables entirely by measuring both datasets simultaneously on the same sample.

 

Catalysts and Catalyst Supports

Investigate structural changes in heterogeneous catalysts during gas adsorption and activation sequences — directly correlating phase composition and crystallinity evolution with adsorption capacity. Identify active phases, deactivation mechanisms, and the structural basis of selectivity during in situ conditions at temperatures up to 623 K. Support porosity calculations from full BET and pore size distribution analysis correlated with real-time XRD data.

 

Metal-Organic Frameworks (MOFs) and Porous Coordination Polymers

Characterize the structural flexibility of breathing MOFs in real time during gas uptake — directly observing the structural transformations (open-to-narrow pore transitions, guest-induced phase changes) that govern the unique adsorption behavior of flexible frameworks. Quantify the pressure thresholds at which structural transitions occur and correlate them with the step-shaped isotherms that define these materials’ adsorption properties.

 

Zeolites and Inorganic Porous Materials

Monitor unit cell parameter changes during CO₂, N₂, and hydrocarbon adsorption in zeolites at each isotherm equilibrium point — directly revealing lattice contraction, expansion, and interplanar spacing changes that reflect host-guest interactions and framework response to adsorption. Simultaneously track adsorption capacity and pore structure across the full micro-to-mesopore range.

 

Energy Storage Materials

Characterize gas adsorption behavior of electrode materials, solid-state electrolytes, and separator materials in direct correlation with their crystallographic state. Study phase evolution during gas exposure, thermal treatment, or activation sequences — critical for understanding cycling-induced structural degradation in battery and supercapacitor materials.

 

Volatile Organic Compound (VOC) Adsorption in Porous Materials

Combine in situ XRD with vapor adsorption isotherms to unravel the structural basis of VOC capture — identifying which crystal planes and structural features contribute to adsorption at specific pressure ranges. The GV model configurations enable direct benzene, toluene, water, and solvent vapor measurements correlated with XRD patterns at each equilibrium point.

 

From fundamental materials research through applied catalyst and adsorbent development, the Nexus Series provides the structural insights needed to understand why materials adsorb the way they do — not just how much.

TYPICAL ANALYSIS RESULTS

Unraveling the VOC Adsorption Mechanism in Organic Cage Materials

Adsorption isotherms of benzene on organic cage materials at 25°C, combined with in situ XRD patterns collected at each adsorption equilibrium point, reveal distinct and systematic structural evolution throughout the adsorption process.

  • 2θ = 5.45°: The diffraction peak is nearly absent during the initial rapid adsorption stage below 1 kPa, indicating that the corresponding crystalline structure contributes negligibly to adsorption. Above 1 kPa, the peak emerges rapidly, suggesting the formation of a new structural arrangement that continuously contributes to adsorption as pressure increases.
  • 2θ = 6.58°: The diffraction peak appears simultaneously with the sharp increase in adsorption uptake below 1 kPa, indicating that the corresponding structure plays a significant role in benzene adsorption. Above 1 kPa, the peak intensity remains relatively stable. Once pressure exceeds 5 kPa, the peak disappears abruptly, indicating the collapse or transformation of the associated structure.
  • 2θ = 8.22°: The diffraction peak intensity decreases rapidly during the initial adsorption stage below 1 kPa, indicating progressive disruption of the corresponding crystalline structure. Above 1 kPa, the peak position gradually shifts toward higher 2θ values, reflecting a reduction in interplanar spacing. In the linear adsorption region above 3 kPa, the peak intensity decreases significantly and eventually disappears completely, suggesting loss of the original structural ordering.

 

Structural Evolution of NaX Zeolite during CO₂ Adsorption

CO₂ adsorption isotherms of NaX zeolite at 25°C, combined with in situ XRD patterns and the corresponding unit-cell parameter (a) determined at each adsorption equilibrium point, reveal a gradual decrease in the unit-cell parameter throughout the adsorption process as CO₂ uptake increases.

  • 2θ = 6.106° — (111) reflection: Intensity decreases continuously with increasing adsorption pressure, while the corresponding interplanar spacing decreases initially and then remains essentially constant after reaching a specific value.
  • 2θ = 30.89° — (555) reflection: Intensity increases during adsorption and reaches a plateau above 20 kPa. Interplanar spacing decreases progressively and stabilizes at pressures above 50 kPa.
  • 2θ = 20.036° — (440) reflection: Intensity decreases rapidly during the initial adsorption stage, coinciding with the steep increase in CO₂ uptake, and becomes stable above 10 kPa. The corresponding interplanar spacing continues to decrease throughout the

SPECIFICATIONS

Parameter Nexus G Core Nexus G Cryo Nexus GV Core Nexus GV Cryo
Adsorbates Non-corrosive gases Non-corrosive gases Non-corrosive gases and vapors Non-corrosive gases and vapors
Adsorption Temperature Range RT to 623 K 85 K to 473 K RT to 623 K 85 K to 473 K

 

Parameter Specification (All Models)
Pressure Measurement System ≥ 5 high-precision pressure transducers: 3 × 1000 Torr, 1 × 10 Torr, 1 × (1 Torr or 0.1 Torr)
Vacuum System Turbomolecular pump + mechanical pump
X-ray Source Sealed-tube Cu target; Co, Mo, and Ag targets available as options
X-ray Tube Power Continuously adjustable, 600 W to 1600 W
Goniometer θ-θ geometry, radius: 170 mm
2θ Scan Range -3° to 156°
Angular Accuracy ≤ ±0.01° (NIST-1976a)
Detector Direct photon-counting 2D array detector; pixel pitch 55 × 55 µm; 256 × 256 pixel array; selectable 0D, 1D, and 2D operating modes
Installation Requirements L 80 in × D 52 in × H 40 in (L 2.0 m × D 1.3 m × H 1.0 m); minimum load-bearing capacity: 1100 lbs (500 kg)

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